Download Advances in Molecular Structure Research by Jeffrey M. Lemm PDF

By Jeffrey M. Lemm

ISBN-10: 0762300256

ISBN-13: 9780762300259

The research of the constitution of molecular structures is an everlasting quarter of analysis. This sequence is dedicated to bringing jointly articles from prime staff within the box that draw jointly fresh theoretical and experimental effects and advances in realizing.

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C , / Figure lB. The solid state molecular structures of Ru6C(CO)14(q6-C6H4Me2) (a) and trans-Ru6C(CO)]l(Ti6-C6H4Me2)2(b); these two molecules have been observed to form both homo-molecular crystals of each type and an hetero-molecular co-crystal in which they are present simultaneously. , ( ( Figure 19. A space-filling representation of the co-crystal formed by Ru6C(CO)14(q6C6HaMe2) and trans-Ru6C(CO)ll(rl6-C6HaMe2)2 (CO-ligands are omitted for sake of clarity); note the AA-BB-AAstacking sequence of molecular layers.

Chem. Brit. 1982, 18, 704. 15. ; Hargittai, M. : Bolinas, CA, 1994, Chapt. XII. 16. This distance is close to twice the van der Waals radius of carbon atom used in the MM3 force field [Allinger, N. ; Yuh, Y. -H. J. Am. Chem. Soc. 1989, 111, 8551]. 17. ; Jemmis, E. ; Osawa, E. J. Am. Chem. Soc. 1991, 113, 4665. 18. (a) Boggs, J. E. Pure & Appl. Chem. 1988, 60, 175. (b) Kutzelnigg, W. J. Mol. Struct. (Theochem) 1989, 61, 11" 1988, 50, 1. " Oberhammer, H. J. Mol. Struct. (Theochem) 1992, 258, 197.

Discussion . . . . . . . . . . . . . . . . . . . A. van der Waals Solids . . . . . . . . . . . . . . . B. Organometallic Crystal Isomerism . . . . . . . . . . . C. Cation-Anion Interactions . . . . . . . . . . . . . D. Hydrogen Bondings . . . . . . . . . . . . . . . Conclusions and Outlook . . . . . . . . . . . . . . . Acknowledgments . . . . . . . . . . . . . . . . . References . .

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